Daniel Nocera - MIT researchers discover a new kind of magnetism
Experiments demonstrate ‘quantum spin liquid,’ which could have
applications in new computer memory storage.
David L. Chandler, MIT News Office
December 19, 2012
Following up on earlier theoretical predictions, MIT researchers have now demonstrated
experimentally the existence of a fundamentally new kind of magnetic behavior, adding to
the two previously known states of magnetism.
Ferromagnetism — the simple magnetism of a bar magnet or compass needle — has been
known for centuries. In a second type of magnetism, antiferromagnetism, the magnetic
fields of the ions within a metal or alloy cancel each other out. In both cases, the materials
become magnetic only when cooled below a certain critical temperature. The prediction and
discovery of antiferromagnetism — the basis for the read heads in today’s computer hard
disks — won Nobel Prizes in physics for Louis Neel in 1970 and for MIT professor emeritus
Clifford Shull in 1994.
“We’re showing that there is a third fundamental state for magnetism,” says MIT professor
of physics Young Lee. The experimental work showing the existence of this new state,
called a quantum spin liquid (QSL), is reported this week in the journal Nature, with Lee as
the senior author and Tianheng Han, who earned his PhD in physics at MIT earlier this year, as lead author.
The QSL is a solid crystal, but its magnetic state is described as liquid: Unlike the other two kinds of magnetism, the magnetic orientations of the
individual particles within it fluctuate constantly, resembling the constant motion of molecules within a true liquid.
Finding the evidence
There is no static order to the magnetic orientations, known as magnetic moments, within the material, Lee explains. “But there is a strong interaction
between them, and due to quantum effects, they don’t lock in place,” he says.
Although it is extremely difficult to measure, or prove the existence, of this exotic state, Lee says, “this is one of the strongest experimental data sets
out there that [does] this. What used to just be in theorists’ models is a real physical system.”
Philip Anderson, a leading theorist, first proposed the concept in 1987, saying that this state could be relevant to high-temperature superconductors, Lee
says. “Ever since then, physicists have wanted to make such a state,” he adds. “It’s only in the past few years that we’ve made progress.”
The material itself is a crystal of a mineral called herbertsmithite. Lee and his colleagues first succeeded in making a large, pure crystal of this material
last year — a process that took 10 months — and have since been studying its properties in detail.
“This was a multidisciplinary collaboration, with physicists and chemists,” Lee explains. “You need both … to synthesize the material and study it with
advanced physics techniques. Theorists were also crucial to this.”
Through its experiments, the team made a significant discovery, Lee says: They found a state with fractionalized excitations, which had been predicted
by some theorists but was a highly controversial idea. While most matter has discrete quantum states whose changes are expressed as whole numbers,
this QSL material exhibits fractional quantum states. In fact, the researchers found that these excited states, called spinons, form a continuum. This
observation, they say in their Nature paper, is “a remarkable first.”
To measure this state, the team used a technique called neutron scattering, which is Lee’s specialty. To actually carry out the measurements, they used
a neutron spectrometer at the National Institute of Standards and Technology (NIST) in Gaithersburg, Md.
The results, Lee says, are “really strong evidence of this fractionalization” of the spin states. “That’s a fundamental theoretical prediction for spin liquids
that we are seeing in a clear and detailed way for the first time.”
It may take a long time to translate this “very fundamental research” into practical applications, Lee says. The work could possibly lead to advances in
data storage or communications, he says — perhaps using an exotic quantum phenomenon called long-range entanglement, in which two widely
separated particles can instantaneously influence each other’s states. The findings could also bear on research into high-temperature superconductors,
and could ultimately lead to new developments in that field, he says.
“We have to get a more comprehensive understanding of the big picture,” Lee says. “There is no theory that describes everything that we’re seeing.”
Subir Sachdev, a professor of physics at Harvard University who was not connected with this work, says that these findings, which have been
anticipated for decades, “are very significant and open a new chapter in the study of quantum entanglement in many-body systems.” The detection of
such states, he says, was an “exceptionally difficult task. Young Lee and his group brilliantly overcame these challenges in their beautiful experiment.”
In addition to Lee and Han, the work was carried out by J.S. Helton of NIST, research scientist Shaoyan Chu of MIT’s Center for Materials Science and
Engineering, MIT chemistry professor Daniel Nocera, Jose Rodriguez-Rivera of NIST and the University of Maryland, and Colin Broholm of Johns
Hopkins University. The work was supported by the U.S. Department of Energy and the National Science Foundation.